کاربرد طرح Box-Behnken برای بهینه سازی پارامترهای حذف کروم شش ظرفیتی از محلول های آبی با استفاده از Fe3O4 بارگذاری شده بر روی کربن فعال تهیه شده از جلبک: مطالعه سینتیک و تعادل

عنوان انگليسی

Application of Box-Behnken design for optimizing parameters of hexavalent chromium removal from aqueous solutions using Fe3O4 loaded on activated carbon prepared from alga: Kinetics and equilibrium study

خلاصه انگلیسی

Diazinon (DZ), an organophosphorus pesticide, has a large consumption for agricultural activities, which its discharge into groundwater and surface is associated with serious concerns for the animal and plants. Thus, the degradation of the mentioned pesticide from an aqueous environment was examined in the electro-Fenton (EF) and sono-electro-Fenton process (SEF) process using SS316/β-PbO2 anode. To characterize the synthesized anode, the analyses, e.g., XRD, SEM, and EDX, were used. The central composite design (CCD) was the method used to assess the efect of selected parameters (DZ concentration=25–75 mg/L, voltage=5–15 V, pH=3–9, and electrolysis time=20–80 min) and their interactions on the DZ degradation in the evaluated system. Detecting the intermediates of DZ degradation was carried out by LC–MS analysis, and its degradation pathways were proposed. To conduct the toxicity tests for inlet and outlet, the growth inhibition percentage of Pseudomonas aeruginosa and Staphylococcus aureus was estimated. SEF process could represent the DZ degradation, COD, and TOC removal efciencies of 92.2%, 73.2%, and 67.4%, respectively. According to kinetic studies, the pseudo-frstorder kinetic (R2>0.99) was detected to be an adequate model for the enlightenment of data of the degradation of DZ by the evaluated system. Finally, DZ is converted into carbon dioxide (CO2( and water (H2O). The results of this study showed that the degradation and mineralization of DZ using the SEF process were successfully carried out.

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