نانو کمپوزیت اکسید آهن/پلی اتیلن گلیگول به عنوان پوشش فیبر ریز استخراج فاز جامد برای تعیین برخی از ترکیبات فرار آلی در آب (2017)

فرجامی نژاد, منوچهر and تهرانی, محمد صابر and آبرومند آذر, پرویز and بهلولی, شهاب and حسین, سید واقف (1395) نانو کمپوزیت اکسید آهن/پلی اتیلن گلیگول به عنوان پوشش فیبر ریز استخراج فاز جامد برای تعیین برخی از ترکیبات فرار آلی در آب (2017). Journal of Separation Science ــ 40 (3). pp. 717-724. شاپا 1615-9306

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Fe3 O4 /polyethylene glycol nanocomposite as a solid-phase microextraction fiber coating for the determination of some volatile organic compounds in water.

English Abstract

A high-performance metal oxide polymer magnetite/polyethylene glycol nanocomposite was prepared and coated in situ on the surface of the optical fiber by sol–gel technology. The magnetite nanoparticles as nanofillers were synthesized by a coprecipitation method and bonded with polyethylene glycol as a polymer. The chemically bonded coating was evaluated for the headspace solid–phase microextraction of some environmentally important volatile organic compounds from aqueous samples in combination with gas chromatography and mass spectrometry. The prepared fiber was characterized by scanning electron microscopy and Fourier transform infrared spectroscopy. The mass ratio of nanofiller and polymer on the coating extraction efficiency, morphology, and stability were investigated. The parameters affecting the extraction efficiency, including the extraction time and temperature, the ionic strength, desorption temperature, and time were optimized. The sol–gelized fiber showed excellent chemical stability and longer lifespan. It also exhibited high extraction efficiency compared to the two types of commercial fibers. For volatile organic compounds analysis, the new fiber showed low detection limits (0.008–0.063 ng/L) and wide linearity (0.001–450 × 104 ng/L) under the optimized conditions. The repeatability (interday and intraday) and reproducibility were 4.13–10.08 and 5.98–11.61%, and 7.35–14.79%, respectively (n = 5). For real sample analysis, three types of water samples (ground, surface, and tap water) were studied

Item Type:Article
زبان سند : انگلیسی
نویسنده مسئول :منوچهر فرجامی نژاد
نویسنده :محمد صابر تهرانی
نویسنده :پرویز آبرومند آذر
نویسنده :شهاب بهلولی
نویسنده :سید واقف حسین
Additional Information:Impact Factor (2015) 2.741 Indexed in: ISI, Pubmed/Medline/Index Medicus, Chemical Abstracts, Abstracts on Hygiene & Communicable Diseases (CABI), Advanced Polymers Abstracts (ProQuest), CCR Database (Clarivate Analytics) , Chimica Database (Elsevier), Chromatography Abstracts (RSC)
کلیدواژه ها (انگلیسی):magnetite nanoparticles; nanocomposites; polyethylene glycol; sol-gel technology; solid-phase microextraction
Subjects:QV pharmacology
Divisions:School of Pharmacy > Department of Pharmacology
ID Code:8550
Deposited By: Dr Shahab Bohlooli
Deposited On:15 Dec 1395 11:09
Last Modified:15 Dec 1395 11:09

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